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CAS 51364-51-3

Tris(Dibenzylideneacetone)Dipalladium(0),[51364-51-3], Pd2(Dba)3, Bis(Dibenzylideneacetone)Palladium(0)

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Tris(dibenzylideneacetone)dipalladium(0),[51364-51-3], Pd2(dba)3,Pd2dba3

Tris(dibenzylideneacetone)dipalladium(0) or Pd2(dba)3 is an organometallic complex based on palladium and dibenzylideneacetone used in organic chemistry. Pd2(dba)3 is used as a source of soluble Pd(0), in particular as a catalyst for various coupling reactions. Examples of reactions using this reagent are the Negishi coupling, Suzuki coupling, Carroll rearrangement, and Trost asymmetric allylic alkylation, as well as Buchwald–Hartwig amination.  Palladium catalyst for chemical coupling

Identification

Name

Tris(dibenzylideneacetone)dipalladium(0)

Synonym

Tris(dibenzylideneacetone)dipalladium,Pd2dba3, Pd2(dba)3

Molecular Structure




Molecular Formula

C51H42O3Pd2

Molecular Weight

915.73

CAS Registry Number

51364-51-3 (52409-22-0)

Pd content

23.2%

 Specification

Analytical pure

Properties

Melting point

152-155 ºC

Water solubility

insoluble;sensitive of air and moisture

Appearance

Purple black powder

Safety Data

Safety Description

S24/25

Application

Paraffin asymmetric arylation, cross coupling reaction, carbon and nitrogen bond formation reaction, ketone α arylation, suzuki reaction


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