Tris(Dibenzylideneacetone)Dipalladium(0),[51364-51-3], Pd2(Dba)3, Bis(Dibenzylideneacetone)Palladium(0)
Tris(dibenzylideneacetone)dipalladium(0),[51364-51-3], Pd2(dba)3,Pd2dba3
Tris(dibenzylideneacetone)dipalladium(0) or Pd2(dba)3 is an organometallic complex based on palladium and dibenzylideneacetone used in organic chemistry. Pd2(dba)3 is used as a source of soluble Pd(0), in particular as a catalyst for various coupling reactions. Examples of reactions using this reagent are the Negishi coupling, Suzuki coupling, Carroll rearrangement, and Trost asymmetric allylic alkylation, as well as Buchwald–Hartwig amination. Palladium catalyst for chemical coupling
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Identification |
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Name |
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Tris(dibenzylideneacetone)dipalladium(0) |
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Synonym |
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Tris(dibenzylideneacetone)dipalladium,Pd2dba3, Pd2(dba)3 |
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Molecular Structure |
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Molecular Formula |
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C51H42O3Pd2 |
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Molecular Weight |
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915.73 |
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CAS Registry Number |
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51364-51-3 (52409-22-0) |
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Pd content |
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23.2% |
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Specification |
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Analytical pure |
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Properties |
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Melting point |
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152-155 ºC |
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Water solubility |
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insoluble;sensitive of air and moisture |
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Appearance |
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Purple black powder |
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Safety Data |
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Safety Description |
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S24/25 |
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Application |
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Paraffin asymmetric arylation, cross coupling reaction, carbon and nitrogen bond formation reaction, ketone α arylation, suzuki reaction |
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2016
© 2016 | PRIVACY POLICY
2019-03-06
2016-11-02